Suitable microorganism-derived polymers include xanthan gum, dextran, succinoglucan, and pullulan. Tested, Effective, Affordable Silicone manufacturers voluntarily support health and environmental testing to provide greater scientific understanding of silicone materials used in consumer and industrial applications. A reactor was charged with 42 g of hexamethyldisiloxane, 100 g of triethoxyphenylsilane, 140 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. From the initial transmittance and transmittance after 40 min, the resistance of UV protective effect against water was evaluated, with the results shown in Table 5. Commercially available examples of the crosslinked organopolysiloxane polymer include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-18A, KSG-19, KSG-016F, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-045Z, KSG-210, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-360Z, KSG-710, KSG-810, KSG-820, KSG-840, KSG-820Z, and KSG-850Z from Shin-Etsu Chemical Co., Ltd. The hydrolytic condensation may be conducted in a solventless system or a solvent, preferably in a solvent. Buy It Now. An emulsion type cream foundation was prepared by stirring and mixing ingredients 1 to 4, part of 5, 6 to 8, 16 to 20, and 21 until uniform, dissolving ingredients 9 and 10 in ingredient 11 uniformly, moderately adding the solution to the mix, emulsifying the mixture, adding ingredients 12 to 15, remainder of 5, and 22 to the emulsion, mixing the contents, and filling a container therewith. Suitable vinyl based polymers include polyvinyl methyl ether and carboxyvinyl polymers. A creamy eye shadow was prepared by step A of mixing ingredients 1 to 4, adding ingredient 5 thereto and mixing and dispersing the contents uniformly, step B of mixing ingredients 6 to 9, step C of adding B to A, and emulsifying the contents. If Mw is too high, the resin becomes less soluble in solvents. The subscript b is a positive number of 0.1 to 0.5, preferably 0.2 to 0.45, more preferably 0.2 to 0.4. The linear acrylic-silicone copolymer may contain in the molecule at least one anionic group selected from pyrrolidinyl, long-chain alkyl, polyoxyalkylene, fluoroalkyl, and carboxyl groups. & Terms of Use. Thus a refractive index was unmeasurable. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. 11. In the prior art, silicone resins are widely used as cosmetic ingredients in make-up cosmetics (e.g., foundations, lipsticks, eye shadows and mascaras), UV care cosmetics, and hair care cosmetics because of their film-forming ability, water resistance, sweat resistance and sebum resistance. The nail enamel overcoat thus obtained was light spreading, increased enamel luster, and was long lasting. Examples 1, 2 and Reference Example 2 demonstrate that sodium hydrogencarbonate and sodium acetate are effective as the reaction catalyst for triphenylsilanol. Suitable skin care cosmetics include toilet water, lotion, milky lotion, cream, cleansing, pack, oil liquid, massage agent, esthetic liquid, esthetic oil, hand cream, lip cream, and wrinkle concealer. A film-forming agent may be added to the cosmetic composition. Since the silicone resin did not dissolve in isododecane, the liquid was white turbid and could not be filtered. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. The ratings ◯ and Δ are acceptable. Suitable weakly basic catalysts include sodium hydrogencarbonate and sodium acetate, which may be used alone or in admixture. The creamy eye shadow thus obtained was light spreading, non-oily, powdery texture-free, and long lasting. Besides, synthetic water-soluble polymers such as polyethylene imine and cation polymers are also included. In the prior art, silicone resins are widely used as cosmetic ingredients in make-up cosmetics (e.g., foundations, lipsticks, eye shadows and mascaras), UV care cosmetics, and hair care cosmetics because of their film-forming ability, water resistance, sweat resistance and sebum resistance. In preparing a silicone resin having compositional formula (1) wherein a is 0.01 to 0.2, the following was confirmed. New Listing [PF] Pendant Production Silicone Epoxy Mold Jewelry Diy Hemisphere Resin. IOTA 54 DIPHENYL DIMETHICONE. C $8.08 to C $17.94. In Patent Documents 5 to 7, they are formulated with a UV absorber or an oil such as a liquid oil having a high polarity as demonstrated by an inorganic value/organic value (JOB) of at least 0.2. The silicone resin of any one of 1 to 4 wherein in formula (1), c is 0, R1 is methyl, and R3 is phenyl. After-sales Service; FAQ; Contact Us; Blog; OTT-1143 Cosmetics Silicone Oil. The powder used herein is not particularly limited with respect to shape (spherical, needle or plate), particle size (fumed, microparticulate, pigment grade), and particle structure (porous or non-porous) as long as it is commonly blended in cosmetics. A reactor was charged with 70 g of hexamethyldisiloxane, 22 g of triphenylsilanol, 210 g of triethoxyphenylsilane, 100 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. Brand New. They are commercially available under the trade name of KSP-100, 101, 102, 105, 300, 411, and 441 from Shin-Etsu Chemical Co., Ltd. The phenylsilicone resin should have a weight average molecular weight (Mw) of 1,000 to 8,000, preferably 2,000 to 7,000, more preferably 2,000 to 6,000. Home; About us; Products. The inventors have found that a phenylsilicone resin comprising specific constituent units is soluble in oily ingredients such as silicone oils and organic oils, able to form a uniform continuous film free of sticky feel and brittleness, and compatible with UV absorbers, and that a cosmetic composition comprising the phenylsilicone resin offers a pleasant feel on use and eliminates secondary staining or transfer to clothes or the like. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. A sun cutting cream was prepared by step A of adding ingredient 7 to part of ingredient 5, mixing uniformly, adding ingredient 8 thereto, dispersing the contents on a bead mill, step B of mixing ingredients 1 to 4, remainder of 5, and 6 until uniform, step C of mixing ingredients 9 to 11, and 13 until uniform, and step D of adding C to B, emulsifying, and adding A and ingredient 12 thereto. Next, 3.5 g of 25% sodium hydroxide aqueous solution and 0.5 g of calcium carbonate were added to the solution to neutralize the acid, after which 22 g of triphenylsilanol and 300 g of isododecane were added to the solution. The label of the cosmetic ingredient list has the following rules: 1 The names of the ingredients identified are in the order of their content in the formula, ie the higher the ranking, the higher the content of this ingredient in the cosmetic. Samples are marked based on the average of each evaluation item, with the results shown in Table 8. Suitable alcohols include lower alcohols of 2 to 5 carbon atoms, polyhydric alcohols of 2 to 10 carbon atoms, sucrose alcohols, and sterols. The cleansing lotion thus obtained was light spreading, gave a moist fresh feeling and exerted a satisfactory cleansing effect. Allegedly these compositions form films having water resistance. Suitable natural dyes include carminic acid, laccaic acid, carthamin, brazilin, and crocin. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. R1, R2 and R3 may be different in the molecule. If d is less than 0.01, the film becomes sticky, and there is a risk that when triphenylsilanol is used for resin preparation, triphenylsilanol is left behind and the resulting resin contains impurities. The cosmetic composition of any one of 9 to 17, which is a skin care cosmetic, hair care cosmetic, make-up cosmetic, UV care cosmetic or antiperspirant. A panel of 50 professional female members evaluated the lipstick with respect to spread upon application, stickiness, color irregularity upon finishing, lasting quality (retention, as evaluated after 8 hours from application) in accordance with the same method as used for the evaluation of the emulsion type cream foundation. You are here: Home. Suitable C1-C8 alkyl groups include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl and octyl. Suitable hydrocarbon oils include linear, branched or volatile hydrocarbon oils. OTT-1143 Cosmetics Silicone Oil. Suitable plant-derived polymers include gum Arabic, tragacanth gum, galactan, carob gum, guar gum, karaya gum, carrageenan, pectin, agar, quince seed (marmelo), starch (rice, corn, potato, wheat), algae colloid, and locust bean gum. Home Silicones, Resins etc Page 1 of 3 Sort by: Worbla Thermoplastic Sheets (All Styles Listed Here) from $ 5.00. The cuticle coating agent thus obtained was light spreading, and effective for preventing the hair from drying up crispy and giving luster and smoothness to the hair. IOTA 201 Methyl Silicone Oil. An O/W cream was prepared by step A of mixing ingredients 1 to 9 while heating, step B of mixing ingredients 10 to 12 and 14 while heating, and step C of slowly adding B to A while stirring, cooling and adding ingredient 13 thereto. Embodiment III is a cosmetic composition containing the phenylsilicone resin in a concentration of 0.1 to 40% by weight, preferably 0.5 to 20% by weight. From China +C $1.00 shipping. A nail enamel was prepared by step A of mixing ingredients 7 to 9, adding ingredients 4 to 6 thereto, and mixing the contents until uniform, step B of adding ingredients 1 to 3 to A and mixing the contents, and step C of adding ingredient 10 to B and mixing the contents. This invention relates to a silicone resin having phenyl group (sometimes referred to as phenylsilicone resin, hereinafter), a method for preparing the same, and a cosmetic composition comprising the same. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. Silicones have revolutionized the application and longevity of most makeup products, including foundation, eyeshadows, blushes, and liquid and pencil eyeliners. Methanesulfonic acid, 2.2 g, was added to the reactor, which was cooled to 10-20° C. With stirring, 100 g of water was added dropwise. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. The subscript “a” is a number of 0 to 0.2, preferably 0.01 to 0.2, more preferably 0.03 to 0.1. The subscript e is a number of 0 to 0.6. The procedure was interrupted because triphenylsilanol did not react. The solution was heated at 130° C. to remove the ethanol formed and excess of water, after which it was cooled. This was followed by distillation in vacuum, controlled dilution with isododecane to a silicone resin concentration of 50%, and filtration, yielding a 50% isododecane solution of a silicone resin having a Mw of 3,410 and consisting of (CH3)3SiO1/2 units, (C6H5)SiO3/2 units and SiO4/2 units in a molar ratio of 0.42:0.35:0.23. Admixture of Crosslinked Organopolysiloxane Polymer and Liquid Oil. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. A W/O liquid foundation was prepared by step A of mixing part of ingredient 4 with ingredient 9 and dispersing ingredient 8 therein uniformly, step B of mixing ingredients 1 to 3, remainder of 4 and ingredients 5 to 7 until uniform, step C of mixing ingredients 10 to 14 and 16 until uniform, and step D of adding C to B while stirring, emulsifying, adding A and ingredient 15 to the emulsion. Using the silicone resin solution obtained in Example, a sun cutting cream was prepared in accordance with the following formulation and preparation method.